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The behavior of a salt will depend upon the acid base properties of the ions present in the salt The ions may lead to solutions of the salt being acidic, basic, or neutral The pH of a solution depends on hydrolysis, a generic term for a variety of reactions with water Some ions will undergo hydrolysis and this changes the pH The reaction of an acid and a base will produce a salt The salt will contain the cation from the base and the anion from the acid In principle, the cation of the base is the conjugate acid of the base, and the anion from the acid is the conjugate base of the acid Thus, the salt contains a conjugate acid and a conjugate base This is always true in principle In some cases, one or the other of these ions is not a true conjugate base or a conjugate acid Just because the ion is not a true conjugate acid or base does not mean that we cannot use the ion as if it were The conjugate base of any strong acid is so weak that it will not undergo any significant hydrolysis; the conjugate acid of any strong base is so weak that it, too, will not undergo any significant hydrolysis Ions that do not undergo any significant hydrolysis will have no effect upon the pH of a solution and will leave the solution neutral The presence of the following conjugate bases Cl , Br , I , NO3 , ClO3 , and ClO4 will leave the + + + + + 2+ 2+ solution neutral The cations from the strong bases, Li , Na , K , Rb , Cs Ca , Sr , and 2+ Ba , while not true conjugate acids, will also leave the solution neutral Salts containing a combination of only these cations and anions are neutral The conjugate base from any weak acid is a strong base and will undergo hydrolysis in aqueous solution to produce a basic solution If the conjugate base (anion) of a weak acid is in a salt with the conjugate of a strong base (cation), the solution will be basic, because only the anion will undergo any significant hydrolysis Salts of this type are basic salts All salts containing the cation of a strong base and the anion of a weak acid are basic salts The conjugate acid of a weak base is a strong acid and it will undergo hydrolysis in an aqueous solution to make the solution acidic If the conjugate acid (cation) of a weak base is in a salt with the conjugate base of a strong acid (anion), the solution will be acidic, because only the cation will undergo any significant hydrolysis Salts of this type are acidic salts All salts containing the cation of a weak base and the anion of a strong acid are acidic salts There is a fourth category, consisting of salts that contain the cation of a weak base with the anion of a weak acid Prediction of the acid base character of these salts is less obvious, because both ions undergo hydrolysis The two equilibria not only alter the pH of the solution, but also interfere with each other Predictions require a comparison of the K values for.

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Here, B, and q are for the mixture, with definitions:

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where a(T) and b are mixture parameters They are functions of composition, but no established theory prescribes the form of this dependence Rather, empirical mixing rules relate mixture parameters to pure-species parameters The simplest realistic expressions are a linear mixing rule for parameter b:

and a quadratic mixing rule for parameter a :

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If you use Crystal Reports 10 or lower version, you can use Barcodesoft UFL (​User Function Library) and code128 barcode fonts. 1. Open DOS prompt. If you are ...

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Dec 5, 2014 · Hello Experts,How could I use code 128 bar code in Crystal Reports? ... The bar code is printed but my barcode reader (Psion Workabout Pro3) ...

with aij = aji The general mole-fraction variable xi is used here because application is to both liquid and vapor mixtures The aij are of two types: pure-species parameters (like subscripts) and interaction parameters (unlike subscripts) Parameter bi is for pure species i The interaction parameter aij is often evaluated from pure-species parameters by combining rules, eg, a geometric-mean rule:

LOMBARDI RULE #1

.

These equations, known as van der Waals prescriptions, provide for the evaluation of mixture parameters solely from parameters for the pure constituent species

Also useful for application of equations of state to mixtures are partial equation-of-state parameters, defined by:

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Since equation-of-state parameters are, at most, functions of temperature and composition, these definitions are in accord with Eq (117) They are independent of the particular mixing rules adopted for the composition dependence of mixture parameters Values of and are implicit in an equation of state, and with Eq (1429) allow calculation of mixture VLE The same basic principle applies as for pure-species VLE, but the a function of T , P , and { y i ) , and a function of T , calculations are more complex With P , and { x i ) ,Eq (1429) represents N relations among the 2N variables: T , P , ( N - 1) yis and ( N - 1)xis Thus, specification of N of these variables, usually either T or P and either the vapor- or liquid-phase composition, allows solution for the remaining N variables by BUBL P, DEW P, BUBL T, and DEW T calculations Cubic equations of state give Z as a function of the independent variables T and p (or V ) Use of such an equation in VLE calculations therefore requires to be given by an equation suited to these variables The derivation of such an equation starts with Eq (1152),written for a mixture with vRreplaced by Eq (640):

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