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occurrence of white spots of mildew fungus on damp leaves, and the existence of yeast infections in the female vagina The rst fossils of fungi are recorded at about the same time as those of land plants (460 500 million years ago) One can reasonably speculate that the rst fungi were probably pathogenic parasites clinging to the moist leaves of the rst land plants Well, what about the animals What about the dinosaurs you may now be asking yourself An animal is any living, breathing (anima) multicellular organism that is not a plant or fungus Animals have eukaryote cells with nuclei, and they must eat other organisms or organic matter in order to survive (We will learn much more about animals in later chapters) The oldest animal fossils are around 600 million years old These rst animals were multicellular ocean-dwellers, such as jelly sh, corals, and seaworms They were all invertebrates (in-VER-tuh-brits) animals without (in-) spines or backbones (vertebr) Delicate jelly sh and other invertebrate animals gracefully oated in the sea during what is technically called the late Pre-Cambrian (pree-KAM-bree-un) Era About 500 million years ago, some animals became vertebrates, developing a backbone Among the rst such vertebrates were jawless shes One hundred million years later, many animals joined the plants and fungi in coming out of the water to live on land This general time span (from about 500 200 million years ago) is called the Paleozoic (pay-lee-uh-ZOH-ik) or ancient life Era This period saw the development of the rst vertebrates ( shes, amphibians, and reptiles), land plants, insects, and vast forests of fern-like trees Amphibians (am-FIB-eeuns) literally live a double life, meaning that they can occupy both (amphi-) land and water Amphibians have a moist skin without any scales They include frogs, toads, newts, and salamanders Giant amphibians roamed as Kings of the Earth, long before the dinosaurs! Reptiles derive their name from the Latin for crawlers Most groups of reptiles (such as turtles, lizards, alligators, and crocodiles) do a lot of creeping and crawling on land We all know that snakes are a group of reptiles that slither, however Reptiles breathe through lungs and usually have skin that is covered by either horny plates or at scales The reptiles evolved from the amphibians and appeared during the middle-to-late Paleozoic Era But they didn t really become the dominant life form on Earth until the Mesozoic (mess-uh-ZOH-ik) or middle (meso-) life (zo) Era The Mesozoic Era is very vivid in people s minds, because it is often nicknamed the Age of Reptiles This period is literally in the middle, because it began about 200 million years ago, just after the Paleozoic Era, with its ancient life, and ended about 65 million years ago, just before the modern.

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The resultant solution, since strontium acetate is soluble, has 0200 M Sr2+ and 0400 M C2H3O2 2+ Ions such as Sr , which come from strong acids or strong bases, may be ignored in this type of problem Ions such as C2H3O2 , from weak acids or bases, will undergo hydrolysis 5 The acetate ion is the conjugate BASE of acetic acid (Ka = 18 10 ) Since acetate is not a strong base this will be a Kb problem, and OH will be produced The equilibrium is: C 2 H 3O + H 2 O 2 0 400 x OH + HC 2H3O2 +x +x

period we nd ourselves in, today The Mesozoic Era is very critical for the fossil record The preserved bones suggest that ying reptiles likely evolved into birds, and small, shrew-like mammals arrived Flowering plants bloomed in the forests and prairies But it is the dinosaurs, or terrible (dino) lizards (saurs), that completely dominated the Mesozoic Era The dinosaurs were reptiles that lived on the land, whereas the pterosaurs (TER-uh-sors) winged lizards were ying reptiles that took command of the sky Mention fossils, and most people probably visualize dinosaur bones! Small wonder, since some dinosaurs were the biggest creatures ever to walk the Earth! Recent evidence suggests that particular types of dinosaurs, such as the duck-billed dinosaurs, traveled in social groups and even cared for their young, after they hatched from eggs (see Figure 34)

If the dinosaurs were so powerful, and some cared for their young, then why did they become extinct a curious person might ask About 65 million years ago, Earth was nearing the end of the Mesozoic Era According to the impact hypothesis, about this time a huge comet or asteroid crashed into the Earth at great speed The force of impact created a massive cloud of dust and debris This great cloud blocked most of the sunlight, killing plants and dramatically cooling Earth s tropical climate Plant-eating dinosaurs had nothing to eat, and died out Thus, meat-eating dinosaurs, which could not devour plant-eating dinosaurs, became extinct as well The mass extinction of all the dinosaurs led to the Cenozoic (sen-uh-ZOHik) or new (ceno) life (zo) Era The Cenozoic Era is sometimes nicknamed The Age of Mammals The reason is because during this past 65 million years or so, leading up to the present day, mammals have become the dominant animals on the Earth Mammals, like birds, probably evolved from reptiles A mammal is an animal that nurses its young with its breasts

Chem Eng Sci, vol 27, pp 1197-1203, 1972 and D B Robinson, Znd Eng Chem Fundam, vol 15, pp 59-64,1976

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CHAPTER 14 Topics in Phase Equilibria Written for pure species i as a vapor, Eq (349) becomes:

gives:

where by Eq (347), For pure species i as a liquid, Eq (353) is written:

In accord with Eqs (342), (343), and (348),

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